Journal of Organometallic Chemistry p. 183 - 194 (1991)
Update date:2022-07-29
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Winkel, Yvar van den
Bastiaans, Harold M. M.
Bickelhaupt, Friedrich
A new route was developed for the synthesis of a specific phosphasilene, 1-(2,4,6-tri-tert-butylphenyl)-2-tert-butyl-2-(2,4,6-tri-isopropylphenyl)phosphasilene (1e).Several novel phosphasilenes (1) with various substituents on phosphorus have been synthesized.The influence of the substituents on the phosphorus and silicon chemical shifts and the stability of the phosphasilenes is analyzed.The chemical reactivity of 1e has been investigated.
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(1994)
