Synthesis of several optically active O-methyl-inosamines and -inosadiamines from L-quebrachitol

Article abstract of DOI:10.1016/0008-6215(91)80116-5

A series of p-toluenesulfonic and methanesulfonic esters of L-quebrachitol have been prepared starting from the di-O-isopropylidene derivative of the cyclitol.Nucleophilic displacement of these sulfonates with azide ion in 2-methoxyethanol produced the az