Journal of Organic Chemistry p. 4631 - 4636 (1991)
Update date:2022-07-29
Topics:
Hugel, Georgette
Royer, Daniel
Sigaut, Francoise
Levy, Jean
Flow thermolysis of 1,2-dehydroaspidospermidine (1) at various temperatures allowed isolation of all four predictable rearrangement products, namely indolenines 2 and 3 and indoles 4 and 5.The structures of the rearranged products were confirmed by chemical and spectroscopic means, particularly HMBC and HMQC NMR techniques.
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