Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 382 - 388 (1991)
Update date:2022-08-04
Topics:
Reznikov, V. A.
Vishnivetskaya, L. A.
Volodarskii, L. B.
Acylation of nitroenamine derivatives of imidazolidin-1-oxyl with carboxylic acid chlorides leads to O-acylhydroximic acid chloride derivatives of 3-imidazolin-1-oxyl.The reaction proceeds apparently through a nitrile oxide.It was shown for the O-benzoyl derivatives that reaction of the obtained acyl chlorides with nucleophilic reagents usually gives products of chlorine atom substitution with simultaneous cleavage of the acyl group.
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