ACYL CHLORIDES OF 2,2,5,5-TETRAMETHYL-3-IMIDAZOLIN-1-OXYL-4-O-ACYLHYDROXIMIC ACIDS

DOI: 10.1007/BF00965436

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 382 - 388 (1991)

Update date:2022-08-04

Topics:

Authors:

Reznikov, V. A.

Vishnivetskaya, L. A.

Volodarskii, L. B.

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Article abstract of DOI:10.1007/BF00965436

Acylation of nitroenamine derivatives of imidazolidin-1-oxyl with carboxylic acid chlorides leads to O-acylhydroximic acid chloride derivatives of 3-imidazolin-1-oxyl.The reaction proceeds apparently through a nitrile oxide.It was shown for the O-benzoyl derivatives that reaction of the obtained acyl chlorides with nucleophilic reagents usually gives products of chlorine atom substitution with simultaneous cleavage of the acyl group.

Full text of DOI:10.1007/BF00965436

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