Journal of Organic Chemistry p. 4337 - 4339 (1991)
Update date:2022-09-26
Topics: Asymmetric synthesis Substitution Reaction Vinylsilane
Mikami, Koichi
Wakabayashi, Hideaki
Nakai, Takeshi
The vinylsilane substitution reaction with glyoxylate and the asymmetric version thereof are described.These new reactions provide α-hydroxy β,γ-unsaturated esters of biological and synthetic importance in high enantiomeric and geometric purity.
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