CYCLOADDITIONS OF 2-(TRIALKYLSILYLOXY)-ALLYLIDENECYCLOPROPANES - SYNTHESIS OF SPIROOCTAN-5-ONES

DOI: 10.1016/0040-4039(91)80812-K

Source and publish data:

Tetrahedron Letters p. 3483 - 3486 (1991)

Update date:2022-08-03

Topics:

Authors:

Thiemann, Thies

Kohlstruk, Stephan

Schwaer, Gerhard

Meijere, Armin de

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Article abstract of DOI:10.1016/0040-4039(91)80812-K

The previously unknown 2-(trialkylsilyloxy)allylidenecyclopropanes 2a-d have been prepared by silylenolization of the easily available cyclopropylidenealkanones 1-R¹ in good yields.Dienes 2a-d readily react with a variety of dienophiles at temp

Full text of DOI:10.1016/0040-4039(91)80812-K

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