Total Synthesis of (+/-)-Clavukerin A: A New Trinorguaiane Sesquiterpene. Biomimetic Synthesis of (+/-)-Clavularin A from (+/-)-Clavukerin A

DOI: 10.1021/jo00024a024

Source and publish data:

Journal of Organic Chemistry p. 6829 - 6832 (1991)

Update date:2022-07-29

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Authors:

Kim, Sung Kee

Pak, Chwang Siek

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Article abstract of DOI:10.1021/jo00024a024

(+/-)-Clavukerin A, 2,8-dimethylbicyclo<5.3.0>deca-5,7-diene, was first synthesized utilizing thermal <2+2> cycloaddition and two carbon ring expansion reactions as key elements. (+/-)-Clavukerin A was transformed, via photooxidation mimicking the biogene

Full text of DOI:10.1021/jo00024a024

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