Synthesis of dl-pyroangolensolide

DOI: 10.1016/0040-4020(95)00375-I

Source and publish data:

Tetrahedron p. 7521 - 7526 (1995)

Update date:2022-07-30

Topics:

Authors:

Fernandez-Mateos, Alfonso

Benito, Manuel Grande

Coca, Gustavo Pascual

Gonzalez, Rosa Rubio

Hernandez, Carolina Tapia

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Article abstract of DOI:10.1016/0040-4020(95)00375-I

A diastereoselective synthesis of dl-pyroangolensolide has been accomplished starting from 2,6-dimethylcyclohexenone in four steps in 62% yield. The key step involves an absolute threo selective aldol reaction.

Full text of DOI:10.1016/0040-4020(95)00375-I

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Product name:(2RS,6SR)-2-<(SR)-3-furylhydroxymethyl>-2,6-dimethylcyclohexanone

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