Diastereoselective Synthesis of 2,3-anti-5-Benzyloxy-2,4-dimethyl-1,3-pentanediols via Cyclic Hydroboration

DOI: 10.1246/bcsj.64.2563

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2563 - 2565 (1991)

Update date:2022-08-05

Topics:

Authors:

Yokoyama, Yasushi

Terada, Yuji

Kawashima, Hideyuki

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Article abstract of DOI:10.1246/bcsj.64.2563

The treatment of (2E,4S)- and (2Z,4S)-1-benzyloxy-5-ethenyloxy-2,4-dimethyl-2-pentene with borane both with and without a catalytic amount of Rh(Ph3P)3Cl gave 2,3-anti-3,4-anti-(2R,3R,4S)- and 2,3-anti-3,4-syn-(2R,3R,4R)-5-benzyloxy-2,4-dimethyl-1,3-penta

Full text of DOI:10.1246/bcsj.64.2563

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Product name:(2E,4R)-1-benzyloxy-2,4-dimethyl-5-ethenyloxy-2-pentene

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