BIS(TERT-BUTYLSULFONYL)ACETYLENE AS A GENERAL SYNTHETIC EQUIVALENT OF ALKYNES IN DIELS-ALDER CHEMISTRY. I: HIGHLY SELECTIVE REDUCTION AND ALKYLATING MONODESULFONYLATION OF Z-1,2-BIS(TERT-BUTYLSULFONYL)ETHENES

DOI: 10.1016/0040-4039(91)80044-7

Source and publish data:

Tetrahedron Letters p. 4579 - 4582 (1991)

Update date:2022-08-05

Topics:

Authors:

Belloch, Jordi

Virgili, Marina

Moyano, Albert

Pericas,Miquel A.

Riera, Antoni

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Article abstract of DOI:10.1016/0040-4039(91)80044-7

Bicyclic (Z)-1,2-Bis(tert-butylsulfonyl)ethenes arising from Diels-Alder reactions of bis(tert-butylsulfonyl)acetylene are efficiently reduced to monosulfones by samarium(II) iodide and alkylatively monodesulfonylated by organolithium compounds.

Full text of DOI:10.1016/0040-4039(91)80044-7

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