BIS(TERT-BUTYLSULFONYL)ACETYLENE AS A GENERAL SYNTHETIC EQUIVALENT OF ALKYNES IN DIELS-ALDER CHEMISTRY. I: HIGHLY SELECTIVE REDUCTION AND ALKYLATING MONODESULFONYLATION OF Z-1,2-BIS(TERT-BUTYLSULFONYL)ETHENES

DOI: 10.1016/0040-4039(91)80044-7

Source and publish data:

Tetrahedron Letters p. 4579 - 4582 (1991)

Update date:2022-08-05

Topics:

Authors:

Belloch, Jordi

Virgili, Marina

Moyano, Albert

Pericas,Miquel A.

Riera, Antoni

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(91)80044-7

Bicyclic (Z)-1,2-Bis(tert-butylsulfonyl)ethenes arising from Diels-Alder reactions of bis(tert-butylsulfonyl)acetylene are efficiently reduced to monosulfones by samarium(II) iodide and alkylatively monodesulfonylated by organolithium compounds.

Full text of DOI:10.1016/0040-4039(91)80044-7

Products guided by the article

Product name:2-(2-Methyl-propane-2-sulfonyl)-3-phenyl-bicyclo[2.2.2]octa-2,5-diene

Cas No:136964-78-8

R&D Labs maybe for 136964-78-8

Hangzhou Gangjin Chemical Co.,Ltd.(expird)

Contact:+86-571-85109780

Address:707 Zhejiang Minhang Bldg., No.290 Zhongshan North Road, Hangzhou 310003, China
Taizhou KEDE Chemical.Co.,Ltd.

Contact:86-576-84613060

Address:Jiangkou Chemical Zoon
Beijing Ribio Biotech Co.,Ltd

Contact:86-10-62664360

Address:Building 10,No.18 AnNingZhuang East Road, GuangHua Pioneer Park,HaiDian District, BeiJing China
Neworld Chemical Co., Ltd Shanghai(expird)

Contact:+86-21-62202658

Address:11F, Blvd 2, No. 1969 PuXing Rd, Shanghai
Zhejiang Chemline International Co., Ltd.

Contact:+86-571-88062298

Address:Hengdian Industry Area, Dongyang, Zhejiang, China

Relevant to this article

Bimetallic nanosized solids with acid and redox properties for catalytic activation of C-C and C-H bonds

Doi:10.1039/C6SC03335K
(2016)
Highly efficient synthesis of allenes from trimethylaluminum reagent and propargyl acetates mediated by a palladium catalyst

Doi:10.1002/ejoc.201403008
(2014)
An efficient synthesis of new diastereomeric enantiopure 1-aminocyclopentane-1,2,4-tricarboxylic acids

Doi:10.1016/j.tetasy.2006.05.001
(2006)
Enantioselective reduction of ketones by polymethylhydrosiloxane in the presence of chiral zinc catalysts

Doi:10.1021/ja990522i
(1999)
On the synthesis of alpha and beta lecithins and their ether analogs

Doi:10.1002/jlac.19677090124
(1967)
Bifunctional acyclic nucleoside phosphonates. 1. Symmetrical 1,3-bis[(phosphonomethoxy)propan-2-yl] derivatives of purines and pyrimidines

Doi:10.1135/cccc20060543
(2006)

Article Doi