
Tetrahedron p. 10119 - 10128 (1991)
Update date:2022-08-02
Topics:
Bowman, W. Russell
Heaney, Harry
Jordan, Benjamin M.
Reductive cyclisations using Bu3SnH include an "oxidation" step if the removal of an acidic proton from the intermediate cyclised radical, by Bu3SnH acting as a base, is favourable. A "pseudo" SRN1 mechanism is proposed.
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