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98-73-7

Basic Information
CAS No.: 98-73-7
Name: 4-tert-Butylbenzoic acid
Article Data: 193
Molecular Structure:
Molecular Structure of 98-73-7 (4-tert-Butylbenzoic acid)
Formula: C11H14O2
Molecular Weight: 178.231
Synonyms: 4-tert-butyl benzoic Acid(PTBBA);p-t-Butylbenzoic acid (PTBBA);P-Tert ¨Cbutylbenzoic Acid;P-tect-butylbenzoic acid;4-Tert-Butyl Benzois Acid(PTBBA);4-tert-butylbenzoic acid;ptbba;internal lubricant;Para-tert-butylbenzoic acid(PTBBA);Description of 4-Tert-Butylbenzoic Acid(PTBBA);P-tert-butyl Benzoic Acid;p-tert-Butylbenzoic acid calcium salt;Magnesium p-t-butylbenzoate;p-tert-Butyl benzoic acid, sodium salt;Benzoic acid, p-tert-butyl-, zinc salt;Benzoic acid, 4-(1,1-dimethylethyl)-, potassium salt;Kyselina p-terc.butylbenzoova [Czech];4-tert-butylbenzoate; zinc(+2) cation;barium(+2) cation; 4-tert-butylbenzoate;Calcium 4-(1,1-dimethylethyl)benzoate;Aluminium 4-(1,1-dimethylethyl)benzoate;Sodium p-tert-butylbenzoate;p-tert-Butyl benzoic acid, potassium salt;Benzoic acid, 4-(1,1-dimethylethyl)-, calcium salt;Benzoic acid, 4-(1,1-dimethylethyl)-, sodium salt;4-tert-butylbenzoate;Potassium p-tert-butylbenzoate;Benzoic acid, 4-(1,1-dimethylethyl)-, aluminum salt;p-t-Butylbenzoic acid, calcium salt;Benzoic acid, 4-(1,1-dimethylethyl)-, zinc salt;Zinc p-t-butylbenzoate;p-tert-Butylbenzoic acid, potassium salt;Calcium p-t-butylbenzoate;aluminum(+3) cation; 4-tert-butylbenzoate;Benzoic acid, 4-(1,1-dimethylethyl)-, barium salt;p-tert-Butylbenzoic acid;Benzoic acid, 4-(1,1-dimethylethyl)-, magnesium salt;4-(Dimethylethyl)benzoic acid, sodium salt;potassium 4-tert-butylbenzoate;Benzoic acid, 4-tert-butyl-;4-09-00-01884 (Beilstein Handbook Reference);Barium 4-(1,1-dimethylethyl)benzoate;P-T-Butylbenzoic Acid;
EINECS: 202-696-3
Density: 1.056 g/cm3
Melting Point: 162-165 °C(lit.)
Boiling Point: 283.3 °C at 760 mmHg
Flash Point: 134.9 °C
Solubility: water: 0.07 g/L (20 oC)
Appearance: white to slightly yellow flakes
Hazard Symbols: HarmfulXn,DangerousN,ToxicT
Risk Codes: 20/22-62-51/53-48/20/21/22-24
Safety: 22-24/25-61-45-36/37/39-28A
Transport Information: UN 2811 6.1/PG 3
PSA: 37.30000
LogP: 2.68230
Synthetic route
939-97-9

4-tert-Butylbenzaldehyde

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With hydrogen bromide; oxygen In acetonitrile at 20℃; for 5h; UV-irradiation;100%
With tert.-butylhydroperoxide; potassium tert-butylate In water at 60℃; for 5h;96%
With N-Bromosuccinimide; oxygen In ethyl acetate at 20℃; Irradiation;93%
98-51-1

4-tert-butyltoluene

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With hydrogen bromide; oxygen In ethyl acetate at 20℃; for 10h; UV-irradiation;100%
With 2-chloroanthracene-9,10-dione; water; oxygen; trifluoroacetic acid In ethyl acetate for 24h; Irradiation;99%
With sulfuric acid; ozone; acetic acid; manganese(II) acetate at 16℃; for 1.66667h;98%

4-tert-butyl-benzoic acid but-2-enyl ester

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃;100%

4-tert-butyl-benzoic acid 2-methyl-allyl ester

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 20℃;100%

cinnamyl 4-tert-butylbenzoate

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With aminomethyl resin-supported N-propylbarbituric acid; tetrakis(triphenylphosphine) palladium(0) In tetrahydrofuran at 60℃;100%
877-65-6

4-tert-Butylbenzyl alcohol

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With bromine; oxygen In acetonitrile for 10h; Irradiation;99%
With N-Bromosuccinimide; oxygen In acetonitrile at 20℃; under 760 Torr; for 1h; Irradiation;99%
With sodium bromate; sodium hydrogen sulfate In acetonitrile for 20h; Heating;95%
1044695-85-3

1-(4-(tert-butyl)phenyl)ethane-1,2-diol

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With oxygen; sodium methylate; silver trifluoromethanesulfonate In tetrahydrofuran; methanol at 37℃; under 760.051 Torr; Sealed tube;99%
With 2-chloroanthracene-9,10-dione; oxygen In ethyl acetate for 20h; Irradiation;80%
26537-19-9

methyl 4-tert-butylbenzoate

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With iodine; aluminium In acetonitrile at 80℃; for 18h;98%
389121-33-9

N,N'-bis-(4-tert-butyl-benzylidene)-hydrazine

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
With poly(diselanediyl-1,2-phenylene); dihydrogen peroxide In tetrahydrofuran for 75h; Heating;97%
772-38-3

4-tert-Butylphenylacetylene

98-73-7

4-(1,1-dimethylethyl)benzoic acid

Conditions
ConditionsYield
Stage #1: 4-tert-Butylphenylacetylene With tert.-butylhydroperoxide; iron(III) chloride hexahydrate; sodium hydroxide In water at 80℃; for 10h;
Stage #2: With hydrogenchloride In water at 20℃;
96%
With oxone; sodium hydrogencarbonate In water; acetonitrile at 20℃; for 7h;94%
With Oxone; trifluoroacetic acid In 1,4-dioxane for 10h; Reflux; Green chemistry;87%
With carbon tetrabromide; water; oxygen In ethyl acetate for 10h; Irradiation;71%
With hydroxylamine hydrochloride; iodine In dimethyl sulfoxide at 100℃; for 8h;61%
Downstream Products
63767-85-1
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  • 4-tert-Butylbenzoic acid     CAS: 98-73-7

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    Product Name: 4-tert-Butylbenzoic acid CAS: 98-73-7 MF: C11H14O2 MW: 178.23 EINECS: 202-696-3 Mol File: 98-73-7.mol 4-tert-Butylbenzoic acid Structure 4-tert-Butylbenzoic acid Chemical Properties Melting point 162-165 °C(l

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Chemistry


IUPAC Name: 4-tert-Butylbenzoic acid
Molecular Formula: C11H14O2
Molecular Weight: 178.23 g/mol
SMILES: O=C(O)c1ccc(cc1)C(C)(C)C Copy 
InChI: InChI=1/C11H14O2/c1-11(2,3)9-6-4-8(5-7-9)10(12)13/h4-7H,1-3H3,(H,12,13)
EINECS: 202-696-3
Classification Code: Reproductive Effect
Product Categories: Intermediates; Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts; Organics; OPLAS; C11 to C12; Carbonyl Compounds; Carboxylic Acids
Index of Refraction: 1.523 
Molar Refractivity: 51.57 cm
Molar Volume: 168.6 cm3
Surface Tension: 37.5 dyne/cm 
Density: 1.056 g/cm
Flash Point: 134.9 °C 
Enthalpy of Vaporization: 55.16 kJ/mol 
Boiling Point: 283.3 °C at 760 mmHg 
Water Solubility: 0.07 g/L (20 °C)
Melting Point: 162-165 °C(lit.)
Vapour Pressure of 4-tert-Butylbenzoic acid (CAS NO.98-73-7): 0.0015 mmHg at 25 °C

Toxicity Data With Reference

Organism Test Type Route Reported Dose (Normalized Dose) Effect Source
mouse LD50 intraperitoneal 242mg/kg (242mg/kg) BRAIN AND COVERINGS: OTHER DEGENERATIVE CHANGES

BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BLOOD: HEMORRHAGE
BG Chemie: Toxicological Evaluations, Five Potential Health Hazards of Existing Chemicals. Vol. 5, Pg. 29, 1993.
mouse LD50 oral 568mg/kg (568mg/kg) PERIPHERAL NERVE AND SENSATION: SPASTIC PARALYSIS WITH OR WITHOUT SENSORY CHANGE

BEHAVIORAL: TREMOR

BLOOD: HEMORRHAGE
BG Chemie: Toxicological Evaluations, Five Potential Health Hazards of Existing Chemicals. Vol. 5, Pg. 29, 1993.
rabbit LD50 skin > 900mg/kg (900mg/kg)   BG Chemie: Toxicological Evaluations, Five Potential Health Hazards of Existing Chemicals. Vol. 5, Pg. 29, 1993.
rat LC50 inhalation > 1900mg/m3/4H (1900mg/m3)   United States Environmental Protection Agency, Office of Pesticides and Toxic Substances. Vol. 8EHQ-0382-0440S,
rat LD50 intravenous > 200mg/kg (200mg/kg)   BG Chemie: Toxicological Evaluations, Five Potential Health Hazards of Existing Chemicals. Vol. 5, Pg. 29, 1993.
rat LD50 oral 473mg/kg (473mg/kg) BEHAVIORAL: CONVULSIONS OR EFFECT ON SEIZURE THRESHOLD

BEHAVIORAL: ATAXIA

LUNGS, THORAX, OR RESPIRATION: DYSPNEA
BG Chemie: Toxicological Evaluations, Five Potential Health Hazards of Existing Chemicals. Vol. 5, Pg. 29, 1993.
rat LD50 skin 300mg/kg (300mg/kg)   BG Chemie: Toxicological Evaluations, Five Potential Health Hazards of Existing Chemicals. Vol. 5, Pg. 29, 1993.

Consensus Reports

Reported in EPA TSCA Inventory.

Safety Profile

Moderately toxic by ingestion. Experimental reproductive effects. An irritant. Combustible when exposed to heat or flame. Incompatible with oxidizing materials. To fight fire, use foam, CO2, dry chemical. When heated to decomposition it emits acrid smoke and irritating fumes.
Hazard Codes:HarmfulXn,DangerousN,ToxicT
Risk Statements: 20/22-62-51/53-48/20/21/22-24 
R20/22:Harmful by inhalation and if swallowed. 
R62:Risk of impaired fertility. 
R51/53:Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R48:Danger of serious damage to health by prolonged exposure. 
R20/21/22:Harmful by inhalation, in contact with skin and if swallowed. 
R24:Toxic in contact with skin.
Safety Statements: 22-24/25-61-45-36/37/39-28A 
S22:Do not breathe dust. 
S24/25:Avoid contact with skin and eyes. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S36/37/39:Wear suitable protective clothing, gloves and eye/face protection. 
S28:After contact with skin, wash immediately with plenty of soap-suds.
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: DG4708000
HazardClass: 6.1
PackingGroup of 4-tert-Butylbenzoic acid (CAS NO.98-73-7): III

Specification

  4-tert-Butylbenzoic acid (CAS NO.98-73-7), its Synonyms are p-tert-Butylbenzoic acid ; Benzoic acid, 4-(1,1-dimethylethyl)- ; Benzoic acid, 4-tert-butyl- ; Benzoic acid, p-tert-butyl- ; Kyselina p-terc.butylbenzoova . It is white to slightly yellow flakes.