Syntheses of W(PhCCPh)3(η1-PPh2CH2PPh2) and W(PhCCPh)3(PPh3) from W(PhCCPh)3(NCCH3)

DOI: 10.1016/0022-328X(92)83089-Z

Source and publish data:

Journal of Organometallic Chemistry p. 257 - 262 (1992)

Update date:2022-08-04

Topics:

Authors:

Yeh, Wen-Yann

Ting, Che-Sheng

Chih, Chu-fang

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Article abstract of DOI:10.1016/0022-328X(92)83089-Z

W(Ph<*>CPh)3(NCCH3) has been synthesized by treating W(PhC<*>CPh)3(CO) with Me3NO in acetonitrile solution.Reactions of W(PhC<*>CPh)3(NCCH3) with (PPh2)2CH2 and PPh3 afford W(PhC<*>CPh)3(η¹-PPh2CH2PPh2) and W(PhC<*>CPh)3(PPh3), respectively.

Full text of DOI:10.1016/0022-328X(92)83089-Z

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