The Stereochemistry of the Aryl Phosphate/Aryl Phosphonate Rearrangement in 1,3,2-Oxazaphospholidine 2-Oxides

DOI: 10.1021/jo00311a017

Source and publish data:

Journal of Organic Chemistry p. 5991 - 5995 (1990)

Update date:2022-07-30

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Authors:

Welch, Steven C.

Levine, Jeffrey A.

Bernal, Ivan

Cetrullo, James

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Article abstract of DOI:10.1021/jo00311a017

On treatment with LDA/THF (aryloxy)phospholidines in the pseudoephedrine/ephedrine series undergo P-O to P-C rearrangement to afford arylphospholidines with retention of configuration at phosphorus.The stereochemistry of each product was assigned by 1H NM

Full text of DOI:10.1021/jo00311a017

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Product name:1,3,2-Oxazaphospholidine, 2-chloro-3,4-dimethyl-5-phenyl-, 2-oxide

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