Journal of Organic Chemistry p. 1956 - 1958 (1992)
Update date:2022-08-05
Topics: Enantioselective synthesis Preparation of Functionalized Dialkylzinc Reagents Iodine-Zinc Exchange Reaction Functionalized Secondary Alcohols
Rozema, Michael J.
AchyuthaRao, Sidduri
Knochel, Paul
Functionalized dialkylzincs are obtained by the reaction of polyfunctional alkyl iodides with Et2Zn in excellent yield.Their treatment with aldehydes, in the presence of the titanium catalyst 6, affords functionalized secondary alcohols with high enantios
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