Chemistry Letters p. 339 - 342 (1992)
Update date:2022-08-05
Topics:
Sakurai, Hideki
Fujii, Takeaki
Sakamoto, Kenkichi
Both cyclic and acyclic acetylenes substituted by two silyl groups on each end undergo facile 1,2-silyl shift in the reaction with cyclopentadienyltricarbonylmanganese under photochemical conditions to give 2,2-disilylvinylidene complexes.Several interest
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