The Reaction of Disilylacetylenes with Cyclopentadienyl Manganese. Formation of Vinylidene Complexes by 1,2-Silyl Shift

DOI: 10.1246/cl.1992.339

Source and publish data:

Chemistry Letters p. 339 - 342 (1992)

Update date:2022-08-05

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Authors:

Sakurai, Hideki

Fujii, Takeaki

Sakamoto, Kenkichi

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Article abstract of DOI:10.1246/cl.1992.339

Both cyclic and acyclic acetylenes substituted by two silyl groups on each end undergo facile 1,2-silyl shift in the reaction with cyclopentadienyltricarbonylmanganese under photochemical conditions to give 2,2-disilylvinylidene complexes.Several interest

Full text of DOI:10.1246/cl.1992.339

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