Tetrahedron p. 905 - 912 (1992)
Update date:2022-08-04
Topics:
Arduini
Pochini
Rizzi
Sicuri
Ugozzoli
Ungaro
The hydrophobic cavity of calix[4]arene (1) has been extended by 'upper rim' functionalization with different alkyl groups. Using p-chloromethylcalix[4]arene (2) as the intermediate, the synthesis of ethyl (4) and p-benzylcalix[4]arenes (5 a-c) was performed. By reaction of 1 with cyclohexene p-cyclohexylcalix[4]arene (6) was obtained. The crystal structure of p-ethylcalix[4]arene (4) was solved.
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Doi:10.1016/j.ejmech.2012.07.013
(2012)Doi:10.1039/c8nj04867c
(2018)Doi:10.1021/acs.orglett.0c03529
(2020)Doi:10.1246/bcsj.65.66
(1992)Doi:10.1016/0022-328X(92)83137-7
(1992)Doi:10.1016/j.tetlet.2012.08.045
(2012)