Advanced Synthesis and Catalysis p. 1941 - 1947 (2012)
Update date:2022-07-29
Topics:
Yu, Han
Xie, Fang
Ma, Zhenni
Liu, Yangang
Zhang, Wanbin
A highly enantioselective copper-catalyzed conjugate addition with triethylaluminium was developed using phosphoramidite ligands bearing a D 2-symmetric biphenyl backbone. For these ligands we demonstrated that the 3,3',5,5'-substituents on the biphenyl backbone can completely reverse the absolute configuration of the products. Copyright
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