Synthesis p. 3765 - 3768 (2009)
Update date:2022-07-29
Topics:
Shen, Kui
Qi, Lixin
Ravula, Mohini
A novel phosphotyrosine analogue that incorporates a phosphatase activity-dependent quinone methide generating motif is synthesized from tyrosine. Following orthoformylation of the phenol moiety of methyl N-Cbz-tyrosinate, the Fmoc-protected 3-difluoromethyl analogue of phosphotyrosine is obtained by functional group transformations. Georg thieme Verlag Stuttgart.
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Doi:10.1039/c39880000524
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