6-Exo Free Radical Cyclization of Acyclic Carbohydrate Intermediates: A New Synthetic Route to Enantiomerically Pure Polyhydroxylated Cyclohexane Derivatives

DOI: 10.1021/jo00035a017

Source and publish data:

Journal of Organic Chemistry p. 2625 - 2631 (1992)

Update date:2022-08-04

Topics:

Authors:

Marco-Contelles, Jose

Pozuelo, Carmen

Jimeno, M. L.

Martinez, Luis

Martinez-Grau, Angeles

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Article abstract of DOI:10.1021/jo00035a017

The 6-exo free radical cyclization of conveniently functionalized acyclic carbohydrate derivatives is a new and efficient method for the asymmetric synthesis of polyhydroxylated cyclohexane compounds (aminocyclitols, pseudosugars).The scope and versatilit

Full text of DOI:10.1021/jo00035a017

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