
Journal of Molecular Structure p. 115 - 124 (1980)
Update date:2022-09-26
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Schnoeckel, H.
SiO reacts with F2 in an argon matrix after photolysis with a high-pressure mercury lamp to form OSiF2.Isotopic splitting (16O/18O and 28Si/29Si) and force constant calculations show that the 6 fundamentals observed can be assigned to the planar molecule OSiF2.The value of the force constant of the SiO double bond, which was calculated as approximately 9 x 1E2 N m-1 in earlier investigations, is confirmed by this work.
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