Tetrahedron Letters p. 2821 - 2822 (1992)
Update date:2022-08-04
Topics:
Nakamura, Hideshi
Ohtoshi, Masaaki
Sampei, Osamu
Akashi, Yuri
Murai, Akio
Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboxylic acid (3a) and the absolute configuration was established as 1R, 2R.
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(1966)
