Synthesis and absolute configuation of (+)-Gonyauline: A modulating substance of bioluminescent circardian rhythm in the unicellular alga gonyaulaux polyedra

DOI: 10.1016/S0040-4039(00)78868-X

Source and publish data:

Tetrahedron Letters p. 2821 - 2822 (1992)

Update date:2022-08-04

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Authors:

Nakamura, Hideshi

Ohtoshi, Masaaki

Sampei, Osamu

Akashi, Yuri

Murai, Akio

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Article abstract of DOI:10.1016/S0040-4039(00)78868-X

Gonyauline, cis-2-(dimethylsulfonio)cyclopropanecarboxylate, an endogenous period-shortening substance of bioluminescent circadian rhythm of the dinoflagellate Gonyaulax polyedra was synthesized from (+)-2-methylthio-1,2-trans-cyclopropanedicarboxylic acid (3a) and the absolute configuration was established as 1R, 2R.

Full text of DOI:10.1016/S0040-4039(00)78868-X

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