Tetrahedron Letters p. 6629 - 6632 (1992)
Update date:2022-09-26
Topics: Kinetics Reaction Conditions Reducing Agent Solvent Effects Hydrosilylation Product Analysis Substrate Catalytic Efficiency Radical Initiator Mechanistic Investigation Radical Chain Reaction Comparative study Reaction yield Silane Radical intermediate Radical trapping
Barton, Derek H. R.
Jang, Doo Ok
Jaszberenyi, Joseph Cs.
The 2,4-bis-thinocarbonate 3 of 1,6-anyhydro-D-glucose 1 can be transformed to the corresponding dideoxy compound 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.
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