Tris(trimethylsilyl)silane and diphenylsilane in the radical chain dideoxygenation of 1,6-anhydro-D-glucose: A comparative study

DOI: 10.1016/S0040-4039(00)61003-1

Source and publish data:

Tetrahedron Letters p. 6629 - 6632 (1992)

Update date:2022-09-26

Topics: Kinetics Reaction Conditions Reducing Agent Solvent Effects Hydrosilylation Product Analysis Substrate Catalytic Efficiency Radical Initiator Mechanistic Investigation Radical Chain Reaction Comparative study Reaction yield Silane Radical intermediate Radical trapping

Authors:

Barton, Derek H. R.

Jang, Doo Ok

Jaszberenyi, Joseph Cs.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(00)61003-1

The 2,4-bis-thinocarbonate 3 of 1,6-anyhydro-D-glucose 1 can be transformed to the corresponding dideoxy compound 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.

Full text of DOI:10.1016/S0040-4039(00)61003-1

Products guided by the article

Product name:(1R,3S,5S)-6,8-dioxabicyclo[3.2.1]octan-3-ol

Cas No:14241-58-8

R&D Labs maybe for 14241-58-8

WUHAN WELLSONG INT'L CO.,LTD

Contact:+86-27-85733560

Address:NO.308,QINGNIAN RD.,WUHAN,CHINA
Hebei Kangtai Pharmaceutical Co.,Ltd

Contact:+86-0317-3512963

Address:Wugang Road,Mengcun of Cangzhou City,Hebei Province ,China
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China
Nanjing Legend Pharmaceutical & Chemical Co., Ltd.

Contact:+86-25-83767696

Address:14-7 Zhongshan Lu Guluo District, Nanjing
Hunan Shineway Enterprise Co., Ltd.

Contact:+86-731-86303875

Address:118, Huanghua International Airport Road, Huanghua Town, Changsha, Hunan 410137, China

Relevant to this article

Pyridone photoelectrocyclizations to pyridophenanthrenes

Doi:10.1016/j.tet.2017.06.062
(2017)
Nickel nanoparticles as racemization catalysts for primary amines

Doi:10.1002/ejic.201300074
(2013)
The stereoselective total synthesis of isocladosorpin

Doi:10.1016/j.tetlet.2013.07.055
(2013)
Induced self-assembly and disassembly of water-soluble alkynylplatinum(ii) terpyridyl complexes with switchable near-infrared (NIR) emission modulated by metal-metal interactions over physiological pH: Demonstration of pH-responsive NIR luminescent probes in cell-imaging studies

Doi:10.1039/c3sc50196e
(2013)
Synthesis, antifungal and antitumor activity of novel (Z)-5- hetarylmethylidene-1,3-thiazol-4-ones and (Z)-5-ethylidene-1,3-thiazol-4-ones

Doi:10.3390/molecules18055482
(2013)
An Efficient and Reliable Catalyst System Using Hemilabile Aphos for B-Alkyl Suzuki-Miyaura Cross-Coupling Reaction with Alkenyl Halides

Doi:10.1002/ejoc.201201602
(2013)

Article Doi