Tris(trimethylsilyl)silane and diphenylsilane in the radical chain dideoxygenation of 1,6-anhydro-D-glucose: A comparative study

DOI: 10.1016/S0040-4039(00)61003-1

Source and publish data:

Tetrahedron Letters p. 6629 - 6632 (1992)

Update date:2022-09-26

Topics: Kinetics Reaction Conditions Reducing Agent Solvent Effects Hydrosilylation Product Analysis Substrate Catalytic Efficiency Radical Initiator Mechanistic Investigation Radical Chain Reaction Comparative study Reaction yield Silane Radical intermediate Radical trapping

Authors:

Barton, Derek H. R.

Jang, Doo Ok

Jaszberenyi, Joseph Cs.

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Article abstract of DOI:10.1016/S0040-4039(00)61003-1

The 2,4-bis-thinocarbonate 3 of 1,6-anyhydro-D-glucose 1 can be transformed to the corresponding dideoxy compound 5 with diphenylsilane 7 as well as with tris(trimethylsilyl)silane 4 in a radical chain reaction.

Full text of DOI:10.1016/S0040-4039(00)61003-1

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