Synthetic approach to stemodin-A novel stereocontrolled construction of the stemodane system by the successive intramolecular Diels-Alder reactions

DOI: 10.1016/S0040-4039(00)61318-7

Source and publish data:

Tetrahedron Letters p. 4581 - 4584 (1992)

Update date:2022-09-26

Topics:

Authors:

Toyota, Masahiro

Seishi, Takashi

Yokoyama, Masaharu

Fukumoto, Keiichiro

Kabuto, Chizuko

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Article abstract of DOI:10.1016/S0040-4039(00)61318-7

The tetracyclic compound 18, possessing the stemodane skeleton, was synthesized from 1,4-cyclohexanedione monoethylene ketal 7. The key steps, 6→5 and 16→18, involve intramolecular Diels-Alder reaction.

Full text of DOI:10.1016/S0040-4039(00)61318-7

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