Synthesis of Chiral N-Protected α-Amino-β-Diketones from α-Diazoketones Derived from Natural Amino Acids

DOI: 10.1016/S0040-4020(01)80473-7

Source and publish data:

Tetrahedron p. 8007 - 8022 (1992)

Update date:2022-08-04

Topics:

Authors:

Ye, Tao Ye, Tao

McKervey, M. Anthony

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Article abstract of DOI:10.1016/S0040-4020(01)80473-7

α-Diazoketols, prepared by condensation of aldehydes or ketones with lithiated optically active α-diazoketones derived from natural amino acids, rearrange to homochiral α-amino-β-diketones on treatment with rhodium(II) acetate.

Full text of DOI:10.1016/S0040-4020(01)80473-7

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