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Reaction of spironaphthalenones with hydroxylamine: Part III. A novel mechanism for the formation of products and trapping of an intermediate

DOI: 10.1016/S0040-4020(01)80513-5

Source and publish data:

Tetrahedron p. 135 - 140 (1993)

Update date:2022-08-03

Topics:

Authors:

Kasturi, Tirumalai R.Kasturi, Tirumalai R.

Kumar, Kaipenchery A.Kumar, Kaipenchery A.

Pragnacharyulu, Palle V. P.Pragnacharyulu, Palle V. P.

Sridevi, GundiSridevi, Gundi

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Article abstract of DOI:10.1016/S0040-4020(01)80513-5

A mechanism involving the intermediacy of nitrene 5, formed from the oxime of spironaphthalenone 1 by acid catalysed dehydration, has been proposed to explain the formation of pyrrolotropones/pyrrolo esters from spironaphthalenones. The initially formed n

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Full text of DOI:10.1016/S0040-4020(01)80513-5

Products guided by the article

Product name:Oxime of 1'-(4-nitrophenyl)-spiro(naphthalene-1(2H),2'(1'H)-naphtho<2,1-b>furan)-2-one

Cas No:146307-45-1

146307-45-1

R&D Labs maybe for 146307-45-1

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