Metallorganische Lewissaeuren. XLVII. Kationische Komplexe + und + mit O-Donoren und N-Donoren (L = Carbonsaeureester, Ethanol, Lacton, Lactam, Diphenylketimin)

DOI: 10.1016/0022-328X(93)80209-T

Source and publish data:

Journal of Organometallic Chemistry p. 219 - 227 (1993)

Update date:2022-08-03

Topics:

Authors:

Milke, Jasna

Missling, Christopher

Suenkel, Karlheinz

Beck, Wolfgang

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Article abstract of DOI:10.1016/0022-328X(93)80209-T

The organometallic Lewis acids (OC)5Re⁺ and Cp(OC)(Ph3P)Ru⁺ form adducts with the O- and N-donors H2O, EtOH, THF, acetone, CH3CN, carboxylic esters, NCCH2CO2Me, BrCH2CO2Me, γ-valerolactone, δ-valerolactam, ε-caprolactam, benzophenone imine.The chiral ethanol complex ⁺BF4^- crystallizes as pairs of enantiomers S_RuS_O and R_RuR_O and the single crystal X-ray determination shows a hydrogen bridge between the oxygen atom of coordinated ethanol and the tetrafluoroborate anion.

Full text of DOI:10.1016/0022-328X(93)80209-T

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