A SIMPLE AND EFFECTIVE ENANTIOMERIC SYNTHESIS OF A CHIRAL PRIMARY AMINE

DOI: 10.1016/S0040-4039(00)77588-5

Source and publish data:

Tetrahedron Letters p. 2259 - 2262 (1993)

Update date:2022-08-04

Topics:

Authors:

Miao, Clara K.

Sorcek, Ronald

Jones, Paul-James

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Article abstract of DOI:10.1016/S0040-4039(00)77588-5

Catalytic reduction of chiral 2-(2-pyridyl)-1,3-oxazolidines and 2-pyridyl imines derived from (R)-phenylglycinol and (R)-valinol afforded high diastereomeric selectivity.Upon oxidative cleavage, the S-primary amine with high ee was obtained.

Full text of DOI:10.1016/S0040-4039(00)77588-5

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