Tetrahedron p. 599 - 605 (1983)
Update date:2022-08-04
Topics:
Jain
Simolike
Jackman
An antibiotic from Streptomyces has been shown to be identical with toromycin and gilvocarcin V. Toromycin has been shown by FT NOE difference spectroscopy to be a C-β-fucofuranoside and to undergo acid-catalyzed rearrangement to an approx. 1:1:2.5 mixture of toromycin and the corresponding C-α-fucofuranoside and C-β-fucopyranoside.
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