Kinetics of dialkylaminium cation radical reactions: Radical clocks, solvent effects, acidity constants, and rate constants for reactions with hydrogen atom donors

DOI: 10.1021/ja00150a012

Source and publish data:

Journal of the American Chemical Society p. 11124 - 11133 (1995)

Update date:2022-08-04

Topics:

Authors:

Horner, John H.

Martinez, Felix N.

Musa, Osama M.

Newcomb, Martin

Shahin, Haifa E.

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Article abstract of DOI:10.1021/ja00150a012

Dialkylaminium cation radical kinetics were studied directly by laser flash photolysis methods. Irradiation of N-hydroxypyridine-2-thione carbamates with 355-nm light gave dialkylaminyl radicals that were protonated to produce dialkylaminium cation radica

Full text of DOI:10.1021/ja00150a012

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