Kinetics of dialkylaminium cation radical reactions: Radical clocks, solvent effects, acidity constants, and rate constants for reactions with hydrogen atom donors

DOI: 10.1021/ja00150a012

Source and publish data:

Journal of the American Chemical Society p. 11124 - 11133 (1995)

Update date:2022-08-04

Topics:

Authors:

Horner, John H.

Martinez, Felix N.

Musa, Osama M.

Newcomb, Martin

Shahin, Haifa E.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/ja00150a012

Dialkylaminium cation radical kinetics were studied directly by laser flash photolysis methods. Irradiation of N-hydroxypyridine-2-thione carbamates with 355-nm light gave dialkylaminyl radicals that were protonated to produce dialkylaminium cation radica

Full text of DOI:10.1021/ja00150a012

Products guided by the article

Product name:2(1H)-Pyridinethione, 1-[[[(5,5-diphenyl-4-pentenyl)methylamino]carbonyl]oxy]-

Cas No:151888-90-3

R&D Labs maybe for 151888-90-3

Zhaodu Fine Chemical Plant

Contact:86-310-8067016

Address:East Fuhua Road,Tiexi Chemical Industrial Estate,Hebei,China
Qingdao XinYongAn Chemicals Co., Ltd

Contact:+86-532-81107967

Address:Chengyang dual-port industrial park by the sea，Qingdao
TIANJIN ZHONGXIN CHEMTECH CO.,LTD.

Contact:86-022-66880623

Address:FINANCIAL STREET WEST BLK 7, #308, NO.52 XINCHENG WEST ROAD, TEDA, TIANJIN, P.R.CHINA
Suzhou Jingye Medicine & Chemical Co., Ltd

Contact:+86-512-66658588

Address:No. 88, Sanlian Street, Jinfeng Road, Suzhou New District, Jiangsu Province, P. R. China
SEA BRGIHT INDUSTRY CO.,LIMITED

Contact:0086 755 8622 3990

Address:Rm 17B3,GuangCaiXinTianDi Bldg,GuiMiao Rd,NanShan District,Shenzhen,China

Relevant to this article

Synthesis, characterization and suppression of impurities during optimization of dabigatran etexilate

Doi:10.3987/COM-13-12746
(2013)
Fluorescent temperature sensing using triarylboron compounds and microcapsules for detection of a wide temperature range on the micro- and macroscale

Doi:10.1002/adfm.201201712
(2013)
Synthesis of novel chromene derivatives of expected antitumor activity

Doi:10.1016/j.ejmech.2012.11.011
(2013)
An efficient synthesis of perfluoroalkenylated aryl compounds via Pincer-Pd catalyzed Heck couplings

Doi:10.1016/j.jfluchem.2012.12.009
(2013)
Improved synthesis of [p-phosphono and p-sulfo]methylphenylalanine. Resolution of [p-phosphono-, p-sulfo-, p-carboxy- and p-N-hydroxycarboxamido-]methylphenylalanine

Doi:10.1016/S0957-4166(00)82297-1
(1992)
Design and synthesis of (S)- and (R)-enantiomers of [4-(2-hydroxy-1- phenylethylimino)pent-2-ol]dimethyltin(iv) and 2,2-dimethyl-4-phenyl-1,3,2- oxazastannolidine: In vitro antitumor activity against human tumor cell lines and in vivo assay of (S)-enantiomers

Doi:10.1039/c2dt32155f
(2013)

Article Doi