Tetrahedron Letters p. 5519 - 5522 (1993)
Update date:2022-09-26
Topics:
McKillop
McLaren
Watson
Taylor
Lewis
A short synthesis of the novel antibiotic aranorosin is described which employs a novel hypervalent iodine-mediated oxidative hydroxylation of a tyrosinal derivative in the key step. A similar procedure was employed to prepare 6'-epiaranorosin, and hence establish the stereochemistry of the natural compound.
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Doi:10.1007/BF00953301
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