Crystal Structure of synthesised together with Other Sandwich Complexes of Tungsten and Molybdenum containing η6-C6F6 or η6-C6H3F3-1,3,5 Ligands, from Atoms of the Metals

DOI: 10.1039/DT9930003097

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 3097 - 3102 (1993)

Update date:2022-07-30

Topics:

Authors:

Barker, John J.

Orpen, A. Guy

Seeley, Andrew J.

Timms, Peter L.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9930003097

Reaction of molybdenum or tungsten atoms with hexafluorobenzene or 1,3,5-trifluorobenzene or with mixtures of these ligands and benzene or 1,3,5-trimethylbenzene gave the new compounds , , , and (M = Mo or W) in yields ranging from <1 to 5percent as stable crystalline solids.A single-crystal X-ray study of W(C6F6)2> showed it to have the same symmetry as and the same W-C bond lengths as in .The 19F and 1H NMR spectra of the mixed-ligand products show interring coupling with large coupling constants which make some of the spectra exceptionally easy to interpret.

Full text of DOI:10.1039/DT9930003097

View Online / Journal Homepage / Table of Contents for this issue

View Online

Products guided by the article

Product name:W(C₆F₆)2

Cas No:153514-11-5

R&D Labs maybe for 153514-11-5

KODI CHEMICAL CO., LTD

Contact:021

Address:Pudong
ZHEJIANG JIANYE CHEMICAL CO.,LTD.

Contact:86-571-64149273,64149234

Address:No. 48, Fuxi Road, Meicheng Town
Shanghai Demand Chemical Co., ltd，China

Contact:86-021-55237578/55239122

Address:Room 3H, No.578, Yingkou Road, Yangpu District, Shanghai, China
GenicBio Limited

Contact:+86-(0)21-3770 9035

Address:Room 301, Building 2, Meijiabang Road 1508, Shanghai China
xuri chemicals co., ltd

Contact:86-516-66656369

Address:The west road of Huaihai, Xuzhou, China

Relevant to this article

The synthesis of pseudo-sugar disaccharides: A Diels - Alder approach to monocarba-disaccharides

Doi:10.1016/S0040-4039(00)61476-4
(1993)
Wurtz-type reductive coupling reaction of allyl bromides and haloorganotins in cosolvent/H₂O(NH₄Cl)/Zn media as a route to allylstannanes and hexaaryldistannanes

Doi:10.1021/om00015a025
(1994)
Guanidine-catalyzed γ-selective morita-baylis-hillman reactions on α,γ-dialkyl-allenoates: Access to densely substituted heterocycles

Doi:10.1055/s-0033-1339471
(2013)
Transition-metal-free access to 2-aminopyridine derivatives from 2-fluoropyridine and acetamidine hydrochloride

Doi:10.1039/c8ob02129e
(2018)
An efficient and regioselective one-pot multi-component synthesis of pyrimido[4,5-d]pyrimidine derivatives in water

Doi:10.1016/j.tetlet.2013.12.095
(2014)
Exoselective 1,3-dipolar [3 + 6] cycloaddition of azomethine ylides with 2-acylcycloheptatrienes: Stereoselectivity and mechanistic insight

Doi:10.1021/acs.orglett.5b00011
(2015)

Article Doi