Tetrahedron Letters p. 8245 - 8248 (1993)
Update date:2022-08-02
Topics:
Rondot, Benoit
Durand, Thierry
Girard, Jean Pierre
Rossi, Jean Claude
Schio, Laurent
et al.
The hex-5-enyl radical cyclization methodology was applied to the formation of optical active prostanoid intermediates 7,8,9 with readily available diacetone-D-glucose as starting material.This result should lead to isoprostaglandins, a novel class of arachidonic acid metabolites obtained by a non-cyclooxygenase mechanism involving free radical-catalysed peroxidation of arachidonic acid.
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