Inside-outside stereoisomerism. 6. Synthesis of trans-bicyclo[4.4.1]undecan-11-one and the first stereoselective construction of the tricyclic nucleus of the ring system of the ingenane diterpenes

DOI: 10.1021/ja00089a006

Source and publish data:

Journal of the American Chemical Society p. 4183 - 4188 (1994)

Update date:2022-08-05

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Authors:

Winkler Winkler

Henegar Henegar

Hong Hong

Williard

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Article abstract of DOI:10.1021/ja00089a006

The intramolecular dioxenone photocycloaddition reaction provides access to compounds which in many cases cannot be otherwise prepared. The application of this methodology to the construction of trans-bicyclo[4.4.1]undecan-11-one, 16, which is ca. 10 kcal

Full text of DOI:10.1021/ja00089a006

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