Siloxanes as temporary tethers in [2 +2] photocycloadditions

DOI: 10.1016/0040-4039(94)88312-2

Source and publish data:

Tetrahedron Letters p. 1657 - 1660 (1994)

Update date:2022-09-26

Topics:

Authors:

Crimmins, Michael T.

Guise, Lisa E.

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Article abstract of DOI:10.1016/0040-4039(94)88312-2

Intramolecular [2+2] photocycloadditions utilizing siloxanes as temporary tethers between an enone and olefin results in the products of an intermolecular photocycloaddition with the selectivity of the intramolecular reaction after cleavage of the temporary tether.

Full text of DOI:10.1016/0040-4039(94)88312-2

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Product name:2-[1-(Allyl-dimethyl-silanyloxy)-hexyl]-5-oxo-cyclopent-1-enecarboxylic acid methyl ester

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