Experiments directed towards the synthesis of anthracyclinones. XXIII A synthesis of fridamycin E

DOI: 10.1071/CH9942135

Source and publish data:

Australian Journal of Chemistry p. 2135 - 2147 (1994)

Update date:2022-08-04

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Authors:

Pausler Pausler

Rutledge

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Article abstract of DOI:10.1071/CH9942135

Fridamycin E (1) has been synthesized in six steps from the anthrarufin mono(chloroallyl) ether (10). The synthesis was based on a titanium-mediated aldol-like addition of a (-)-menthyl acetate enolate to the ketone (9). Similar additions to the aldehydes

Full text of DOI:10.1071/CH9942135

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