Tetrahedron p. 10095 - 10106 (1994)
Update date:2022-08-04
Topics:
Verstegen-Haaksma, Anja A.
Swarts, Henk J.
Jansen, Ben J. M.
Groot, Aede de
Conjugate addition of cyanide and allyl nucleophiles to S-(+)-carvone followed by annulation with methyl vinyl ketone gave the substituted decalones 2 and 3 stereoselectively.Both decalones were transformed into (-)-Ambrox via modification of the sidechain, methylation, conversion of the isopropenyl group and cyclization.
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