Preparation of alkyl-substituted indoles in the benzene portion. Part 12. Enantiospecific synthesis of hapalindole O

DOI: 10.1248/cpb.42.1393

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 1393 - 1398 (1994)

Update date:2022-07-30

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Authors:

Sakagami

Muratake

Natsume Natsume

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Article abstract of DOI:10.1248/cpb.42.1393

An important chiral ketone derivative, (3S,4R)-3-methyl-4-pivaloyloxy-3- vinylcyclohexan-1-one (16) was prepared from (R)-(-)-carvone (10) using a stereo-controlled conjugate addition of the vinyl group to (R)-3-methyl-6- (1-methylethylidene)-4-pivaloylox

Full text of DOI:10.1248/cpb.42.1393

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