Cis-(S)Ph2)>: A New Catalyst for Methanol Carbonylation

DOI: 10.1039/c39950000197

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 197 - 198 (1995)

Update date:2022-07-29

Topics:

Authors:

Baker, Michael J.

Giles, Martin F.

Orpen, A. Guy

Taylor, Michael J.

Watt, Robert J.

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Article abstract of DOI:10.1039/c39950000197

The complex cis-(S)Ph2)> is eight times more active than the classic Monsanto catalyst - for the carbonylation of methanol at 185 deg C offering the first promoted system effective under conditions which allow industrially realistic rates; the X-ray crystal structure of the analogue cis-(S)Ph2)> is reported together with in situ spectroscopic evidence for species in the catalytic cycle.

Full text of DOI:10.1039/c39950000197

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