Silylcupration of allenes followed by reaction with enones. A new strategy for the synthesis of methylenecyclopentanols

DOI: 10.1016/S0040-4039(99)01264-2

Source and publish data:

Tetrahedron Letters p. 6649 - 6652 (1999)

Update date:2022-08-03

Topics:

Authors:

Barbero, Asuncion

Garcia, Carlos

Pulido, Francisco J.

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Article abstract of DOI:10.1016/S0040-4039(99)01264-2

Silylcupration of allene using phenyldimethylsilyl-copper followed by conjugated addition to α,β-unsaturated ketones affords oxoallylsilanes with different substitution patterns. When the former oxoallylsilanes are treated with a Lewis acid they undergo h

Full text of DOI:10.1016/S0040-4039(99)01264-2

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