Stereocontrolled Aldol Additions to α-Methylene-β-Alkoxy Aldehydes: Application to the Synthesis of a C13-C25 Segment of Bafilomycin A1.

DOI: 10.1016/0040-4039(94)02205-P

Source and publish data:

Tetrahedron Letters p. 175 - 178 (1995)

Update date:2022-09-26

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Authors:

Paterson, Ian

Bower, Shelley

McLeod, Malcolm D.

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Article abstract of DOI:10.1016/0040-4039(94)02205-P

A boron-mediated, syn-aldol coupling between ethyl ketone 8 and aldehyde 9, followed by directed hydrogenation at C₁₆ and acetonide hydrolysis, gives the C₁₃-C₂₅ segment 6 of bafilomycin A₁.

Full text of DOI:10.1016/0040-4039(94)02205-P

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