Organometallic Liquid Crystals Based on Octahedral Rhodium(III)

DOI: 10.1039/DT9950000317

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 317 - 318 (1995)

Update date:2022-08-04

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Authors:

Rourke, Jonathan P.

Bruce, Duncan W.

Marder, Todd B.

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Article abstract of DOI:10.1039/DT9950000317

Reaction of mesomorphic alkynes with led to the Rh(III) complexes mer,trans- which are liquid crystalline; they are rare examples of rod-like liquid crystals based on an octahedral metal centre and represent a unique homologous series of mesomorphic metal complexes containing a hydrido function.

Full text of DOI:10.1039/DT9950000317

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Product name:mer,trans-[RhH(CCC₆H₄O₂CC₆H₄OC₈H₁₇)2(PMe₃)3]

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