Stereocontrolled conversion of 3-unsubstituted isoxazole compounds into Z-β-siloxyacrylonitriles. A new method for the regioselective synthesis of β-enaminoketones

Article abstract of DOI:10.1080/00397919508012661

The stereoselective synthesis of Z-β-siloxyacrylonitriles via base-induced ring cleavage of isoxazole precursors is described. Z-β-siloxyacrylonitriles react with organolithium compounds to give high yields of β-enaminoketones 1.

Full text of DOI:10.1080/00397919508012661

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Synthetic Communications: An
International Journal for Rapid
Communication of Synthetic
Organic Chemistry
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Stereocontrolled Conversion
of 3-Unsubstituted Isoxazole
Compounds into Z-β-
Siloxyacrylonitriles. A New
Method for the Regioselective
Synthesis of β-Enaminoketones
B. González a , A. M. González a & F. J. Pulido a
a Departamento de Química Orgánica , Universidad
de Valladolid , 47011, Valladolid, Spain
Published online: 23 Sep 2006.
To cite this article: B. González , A. M. González & F. J. Pulido (1995)
Stereocontrolled Conversion of 3-Unsubstituted Isoxazole Compounds into
Z-β-Siloxyacrylonitriles. A New Method for the Regioselective Synthesis of β-
Enaminoketones, Synthetic Communications: An International Journal for
Rapid Communication of Synthetic Organic Chemistry, 25:7, 1005-1014, DOI:
10.1080/00397919508012661
To link to this article: http://dx.doi.org/10.1080/00397919508012661
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