Synthesis and Characterisation of Manganese(II) Chalcogenolato Complexes. Crystal and Molecular Structure of infinite>

DOI: 10.1039/DT9950001645

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1645 - 1648 (1995)

Update date:2022-08-03

Topics:

Authors:

Bochmann, Manfred

Powell, Anne K.

Song, Xuejing

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001645

A series of manganese(II) complexes <> (E = Se, R' = Me or t-Bu; E = Te, R' = Me) have been prepared by photolysis of 2(thf)> (thf = tetrahydrofuran) with the corresponding sterically demanding arenechalcogenols 2,4,6-R'3C6H2EH.Complexes with R' = Me form co-ordination polymers which are soluble only in strongly co-ordinating solvents, while complexes with R' = t-Bu are dimeric and readily dissolve in less polar solvents such as toluene.The complexes react with Lewis bases (PMe3, 2,2'-bipyridyl) to form tetrahedral or octahedral adducts, depending on the steric requirements of the arenechalcogenolate ligands.The structure of <_infinite> was determined by X-ray diffraction.The compound forms a one-dimensional infinite chain with bridging selenolate ligands which surround the metal centre in a flattened tetrahedral geometry.

Full text of DOI:10.1039/DT9950001645

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Mn(Se(2,4,6-tri-tert-butylphenyl))2(Me₂PCH₂CH₂PMe₂)]

Cas No:165466-48-8

R&D Labs maybe for 165466-48-8

Sinoway Industrial Co., Ltd.

website:http://www.china-sinoway.com

Contact:+86-592-5853819

Address:16/F,Huicheng Comm,Complex,No839 XiaHe Rd, Xiamen,China
ChangZhou XiaQing Chemical Co., Ltd.

Contact:+86-519-88721665

Address:3# Hengluo Road, Henglin Town, Changzhou City, Jiangsu Province，China
feixia327@163.com

Contact:--

Address:80G, No.1 Building, Guodu Development Mansion, No. 182 Zhaohui Road, Hangzhou City, Zhejiang Province,China.
Hangzhou Fandachem Co.,Ltd

Contact:+86-158-5814-5714

Address:No.9 YanAn Road,Hangzhou,Zhejiang,China
Nanjing yieldpharma co.ltd

Contact:13813902930 025-52714267

Address:20 Fengji Road, Yuhua Economic Development Zone, Nanjing, Jiangsu, P. R. China

Relevant to this article

Divalent Lanthanide Chemistry: Three Synthetic Routes to Samarium(II) and Ytterbium(II) Bis(phosphido) Species Including the Structural Characterization of Yb[PPh2](thf)4 and Sm[PPh2]2(N-MeIm)4

Doi:10.1021/ic00122a003
(1995)
Synthesis and absolute configuration of desmarestene, the gamete-releasing and gamete-attracting pheromone of the brown algae Desmarestia aculeata and D.firma (Phaeophyceae)

Doi:10.1016/0040-4020(95)00435-B
(1995)
Metallorganische Verbindungen des Kupfers VIII. Untersuchungen ueber die Koordinationschemie von heteroatomverbrueckten Bisalkinen am Beispiel von Kupfer(I)-halogenid- und -trifluormethylsulfonat-Komplexen

Doi:10.1016/0022-328X(95)05437-T
(1995)
Erratum: Isolation of a metabolite from the pks island provides insights into colibactin biosynthesis and activity (Organic Letters (2015) 17:6 (1545-1548) DOI: 10.1021/acs.orglett.5b00432)

Doi:10.1021/acs.orglett.5b01056
(2015)
Doi:10.1021/ja01141a520
(1952)
Benzothiazole Schiff-bases as potential imaging agents for β-amyloid plaques in Alzheimer's disease

Doi:10.1007/s00044-012-0416-0
(2013)

Article Doi