Synthesis and Characterisation of Manganese(II) Chalcogenolato Complexes. Crystal and Molecular Structure of infinite>

DOI: 10.1039/DT9950001645

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1645 - 1648 (1995)

Update date:2022-08-03

Topics:

Authors:

Bochmann, Manfred

Powell, Anne K.

Song, Xuejing

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9950001645

A series of manganese(II) complexes <> (E = Se, R' = Me or t-Bu; E = Te, R' = Me) have been prepared by photolysis of 2(thf)> (thf = tetrahydrofuran) with the corresponding sterically demanding arenechalcogenols 2,4,6-R'3C6H2EH.Complexes with R' = Me form co-ordination polymers which are soluble only in strongly co-ordinating solvents, while complexes with R' = t-Bu are dimeric and readily dissolve in less polar solvents such as toluene.The complexes react with Lewis bases (PMe3, 2,2'-bipyridyl) to form tetrahedral or octahedral adducts, depending on the steric requirements of the arenechalcogenolate ligands.The structure of <_infinite> was determined by X-ray diffraction.The compound forms a one-dimensional infinite chain with bridging selenolate ligands which surround the metal centre in a flattened tetrahedral geometry.

Full text of DOI:10.1039/DT9950001645

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Mn(Se(2,4,6-tri-tert-butylphenyl))2(Me₂PCH₂CH₂PMe₂)]

Cas No:165466-48-8

R&D Labs maybe for 165466-48-8

Xi'an Kaixiang Photoelectric Technology Co., Ltd

website:http://www.kxmaterials.com/

Contact:86-29-15991651477

Address:Building 6, Biopharmaceutical Industry R&D Cluster Base, No. 16, Caotang 4th Road, Caotang Science and Technology Industrial Base, High-tech Zone, Xi'an City, Shaanxi Province, China
NINGXIA DARONG CHEMICALS & METALLURGY CO.,LTD.

Contact:86-952-2179751

Address:Darong Road, Dawukou, Shizuishan, Ningxia 753001, China
HUNAN CHEMAPI BIOLOGICAL TECHNOLOGY CO.,LTD.

Contact:+86-186-02659358

Address:1004, building 3, Wanke Jinsemaitianyuan, 498 Guitang Road, Yuhua District, Changsha City, Hunan Province, China
Hefei EnliPharma Tecnology Co.,Ltd

Contact:0086-551-66399836

Address:Qing Cheng ShuiXiang Building 805, Mengcheng North Road , ShuangFeng Economic Development Zone Anhui HeFei
Jiacheng-Chem Enterprises Limited(expird)

Contact:86-571-86711508

Address:19 Floor, CIBC Holley International Building, No. 198,Wuxing Road, Hangzhou, China,310020

Relevant to this article

Divalent Lanthanide Chemistry: Three Synthetic Routes to Samarium(II) and Ytterbium(II) Bis(phosphido) Species Including the Structural Characterization of Yb[PPh2](thf)4 and Sm[PPh2]2(N-MeIm)4

Doi:10.1021/ic00122a003
(1995)
Synthesis and absolute configuration of desmarestene, the gamete-releasing and gamete-attracting pheromone of the brown algae Desmarestia aculeata and D.firma (Phaeophyceae)

Doi:10.1016/0040-4020(95)00435-B
(1995)
Metallorganische Verbindungen des Kupfers VIII. Untersuchungen ueber die Koordinationschemie von heteroatomverbrueckten Bisalkinen am Beispiel von Kupfer(I)-halogenid- und -trifluormethylsulfonat-Komplexen

Doi:10.1016/0022-328X(95)05437-T
(1995)
Erratum: Isolation of a metabolite from the pks island provides insights into colibactin biosynthesis and activity (Organic Letters (2015) 17:6 (1545-1548) DOI: 10.1021/acs.orglett.5b00432)

Doi:10.1021/acs.orglett.5b01056
(2015)
Doi:10.1021/ja01141a520
(1952)
Benzothiazole Schiff-bases as potential imaging agents for β-amyloid plaques in Alzheimer's disease

Doi:10.1007/s00044-012-0416-0
(2013)

Article Doi