Polyhedron p. 1607 - 1614 (1995)
Update date:2022-08-04
Topics:
Thomas, K. R. Justin
Chandrasekhar, V.
Scott, S. R.
Cordes, A. W.
Synthesis and characterization of isotypical compounds N3P3Ph2Pz4*MX2 (M=Cu, X=Cl or Br; M=Co, X=Cl) are reported. The X-ray crystal structure of N3P3Ph2Pz4*CoCl2*0.5CH2Cl2 is described. The structure is a distorted trigonal bipyramid in which the cobalt atom is coordianted by a ligand ,olecule through the two nongeminal pyrazolyl pyridinic nitrogens at the equatorial sites and a cyclophosphazene ring nitrogen at the axial position. The remaining axial and equatorial positions are occupied by the two chlorine atoms.
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