Synthesis of Optically Active α-Methylene γ-Butyrolactones and (+)-Mintlactone

DOI: 10.1016/0040-4020(95)00236-2

Source and publish data:

Tetrahedron p. 5831 - 5846 (1995)

Update date:2022-08-02

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Authors:

Crisp, Geoffrey T.

Meyer, Adam G.

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Article abstract of DOI:10.1016/0040-4020(95)00236-2

The combination of baker's yeast reductions of β-keto carbonyls, vinyl triflate formation and a palladium-catalysed, intramolecular, carbonylative coupling affords optically active α-methylene γ-butyrolactones.The synthesis of the unnatural (+)-mintlacton

Full text of DOI:10.1016/0040-4020(95)00236-2

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