Synthesis of 6-NC5H3Me2-2,6)(η6-C6H5Me)>: Photoelectron Spectra and Electronic Structure of some Transition-metal η6-2,6-Dimethylpyridine Complexes

DOI: 10.1039/DT9950001873

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1873 - 1878 (1995)

Update date:2022-08-04

Topics:

Authors:

Ashmore, Jennifer

Green, Jennifer C.

Green, Malcolm L. H.

Smith, Marcus Lovell

Mehnert, Christian

Wucherer, Edward J.

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Article abstract of DOI:10.1039/DT9950001873

Synthesis of the mixed-ring sandwich compound 6-NC5H3Me2-2,6)(η⁶-C6H5Me)> is reported.Photoelectron spectroscopic studies of 6-NC5H3Me2-2,6)2>, where M = Ti, V, Cr or Mo and 6-NC5H3Me2-2,6)(η⁶-C6H5Me)> established that these sandwich compounds are electronically very similar to the bis(arene) analogues, and that 2,6-dimethylpyridine is a better δ acceptor than benzene.

Full text of DOI:10.1039/DT9950001873

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