A DIRECT SYNTHESIS OF 1,3-BIS(BROMOMAGNESIO)PROPANE

DOI: 10.1016/S0040-4039(00)87142-7

Source and publish data:

Tetrahedron Letters p. 1497 - 1500 (1982)

Update date:2022-07-30

Topics:

Authors:

Seetz, J.W.F.L.

Hartog, F.A.

Boehm, H.P.

Blomberg, C.

Akkerman, O.S.

Bickelhaupt, F.

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Article abstract of DOI:10.1016/S0040-4039(00)87142-7

Careful addition of 1,3-dibromopropane (2) to magnesium in Et2O yields 1,3-bis(bromomagnesio)propane (1) which is purified via "magnesacyclobutane" (5).Reactions of 1 with H2O, CO2, HgBr2 and Me3SnCl are reported.MgBr2 catalyzes the decomposition of 1 to allylmagnesium bromide (4).

Full text of DOI:10.1016/S0040-4039(00)87142-7

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