1,4-dioxene in organic synthesis: Generation and reactivity of epoxydioxenes

DOI: 10.1016/0040-4039(95)01307-4

Source and publish data:

Tetrahedron Letters p. 6475 - 6478 (1995)

Update date:2022-08-03

Topics:

Authors:

Baylon, Christophe

Hanna, Issam

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Article abstract of DOI:10.1016/0040-4039(95)01307-4

Oxidation of various alkyldioxens with dimethyldioxirane is described. While pure epoxides were isolated from 4-dioxenylcyclohexanone 10 and diether 9, vinyldioxenes 11-14 gave the corresponding epoxide rearrangement products, α-ketal aldehydes 20-24, in excellent yields.

Full text of DOI:10.1016/0040-4039(95)01307-4

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