1,4-dioxene in organic synthesis: Generation and reactivity of epoxydioxenes

DOI: 10.1016/0040-4039(95)01307-4

Source and publish data:

Tetrahedron Letters p. 6475 - 6478 (1995)

Update date:2022-08-03

Topics:

Authors:

Baylon, Christophe

Hanna, Issam

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(95)01307-4

Oxidation of various alkyldioxens with dimethyldioxirane is described. While pure epoxides were isolated from 4-dioxenylcyclohexanone 10 and diether 9, vinyldioxenes 11-14 gave the corresponding epoxide rearrangement products, α-ketal aldehydes 20-24, in excellent yields.

Full text of DOI:10.1016/0040-4039(95)01307-4

Products guided by the article

Product name:3-(5,6-Dihydro-[1,4]dioxin-2-yl)-2,2,4-trimethyl-cyclohex-3-enone

Cas No:171254-66-3

R&D Labs maybe for 171254-66-3

Wuxi Olite Chemical Co., Ltd.

Contact:86-510-82853889

Address:Rm.3732, No.18-2,Yonghe Rd.,Wuxi,Jiangsu,214023,China
waho int'l company

Contact:+86-579-85206992

Address:No 451 chouzhou north road ,room 1106 int'l business center , yiwu ,china
Suzhou HeChuang Chemical Co.,Ltd.

Contact:+86-512-88800520

Address:No.9 Guanchao Rd,Changshu Advanced Materials Industy Park
Huangshi Shennong Chemical Technology Co., Ltd

Contact:+86-714-3072290

Address:Eastern industrial park , Tieshan district , Huangshi city ,Hubei province , China
Shochem(Shanghai) Co., Ltd

website:http://www.shochem.com

Contact:021-50800795

Address:No.1043, Halei Rd, Zhangjiang Hi-Tech Park, Shanghai, Postcode 201203, China

Relevant to this article

Asymmetric hydroformylation catalysed by platinum complexes of new chiral bisphosphites

Doi:10.1039/a608436b
(1997)
Ring Expansion of 4-Alkynylcyclobutenones. Synthesis of Enantiomerically Pure Pyranoquinones from 4-(4-Oxo-1,6-enynyl)-4-hydroxycyclobutenones and 4-(4-Oxo-1,6-dialkynyl)-4-hydroxycyclobutenones

Doi:10.1021/jo00125a037
(1995)
β-Lactams from tetrahydro-1,2-oxazine-3,6-diones, and a labelling study of the product stereochemistry

Doi:10.1016/0040-4020(95)00737-S
(1995)
Stereochemistry of the [4 + 2] cycloaddition of diarylselenoketones with conjugated dienes

Doi:10.1021/ja00149a015
(1995)
Chemistry of diamino-ligated methylpalladium(II) alkoxide complexes: Syntheses, X-ray crystal structures, and hydrogen-bond formation

Doi:10.1021/ja00149a017
(1995)
Glycan-specific metabolic oligosaccharide engineering of C7-substituted sialic acids

Doi:10.1002/anie.201108809
(2012)

Article Doi