Catalytic asymmetric hydrogenation of α-(acetamido)acrylates using TRAP trans-chelating chiral bisphosphine ligands: Remarkable effects of ligand P-substituent and hydrogen pressure on enantioselectivity

DOI: 10.1246/bcsj.73.2571

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2571 - 2578 (2000)

Update date:2022-07-30

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Authors:

Kuwano Kuwano

Sawamura

Ito Ito

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Article abstract of DOI:10.1246/bcsj.73.2571

The catalytic asymmetric hydrogenation of α-(acetamido)acrylates was carded out with the rhodium complexes prepared from [Rh(cod)₂]BF₄ and trans-chelating chiral bisphosphine ligands, (S,S)-2,2'-bis[(R)-1-(dialkylphosphino)ethyl]-1,1

Full text of DOI:10.1246/bcsj.73.2571

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